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鈷的二苯甲酰甲烷配合物:晶體結(jié)構(gòu)及其軸向置換反應(yīng)
Cobalt (Ⅱ) can form complexes with Hdbm in different environments. Hdbm reacted with cobalt nitrate to give complex 1 [Co(dbm)2 @ 2H2O]. When complex 1 reacted with pyridine, α-stilbazole or 4, 4'-bipyridine respectively, complex 2 [Co(DBM)2Py2] (Py= pyridine), 3 [Co(DBM)2Sbz2] (Sbz =α-stilbazole) or 4 [Co(DBM)2BPy] n was obtained in turn through metathetical reaction. The coordination modes are octahedral polyhedrons. In the crystal structures, the two dbms take the plane position and two other donor molecules take the axial position. CCDC: 196070 for complex 2; 186859 for complex 3.
作 者: 盧會杰 高潔 杜晨霞 樊耀亭 侯紅衛(wèi) 丁德剛 翟俊玲 作者單位: 盧會杰,高潔,杜晨霞,樊耀亭,侯紅衛(wèi),丁德剛(鄭州大學(xué)化學(xué)系,鄭州,450052)翟俊玲(三門峽職業(yè)技術(shù)學(xué)院,三門峽,472000)
刊 名: 無機(jī)化學(xué)學(xué)報(bào) ISTIC SCI PKU 英文刊名: CHINESE JOURNAL OF INORGANIC CHEMISTRY 年,卷(期): 2003 19(2) 分類號: O614.81 關(guān)鍵詞: 二苯甲酰甲烷 鈷配合物 晶體結(jié)構(gòu) 軸向置換反應(yīng) dibenzoylmethane cobalt complexes crystal structures axial metathetical reaction【鈷的二苯甲酰甲烷配合物:晶體結(jié)構(gòu)及其軸向置換反應(yīng)】相關(guān)文章:
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